Bimbala Das wore a silk saree for the ceremony Wednesday at Atala village near the Orissa state capital Bhubaneswar.
Priests chanted mantras to seal the union, but the snake failed to come out of a nearby ant hill where it lives, the Press Trust of India (PTI) said on Friday.
A brass replica snake stood in for the hesitant groom.
"Though snakes cannot speak nor understand, we communicate in a peculiar way," Das, 30, told the agency.
"Whenever I put milk near the ant hill where the cobra lives, it always comes out to drink.
"I always get to see it every time I go near the ant hill. It has never harmed me," she added.
Villagers welcomed the wedding in the belief it would bring good fortune and laid on a feast for the big day.
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Remember: all cultures are equal, and if you think there's something wrong with marrying a snake you're an intolerant Nazi